Sulfide stress cracking ssc vs hydrogen induced cracking. They found that the scc cracks usually initiate from corrosion pits and pits nucleate from sulfides. An industry value that has been developed is nace mr01. Mar 27, 2014 the results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking.
In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. Al bronze towards stress corrosion cracking has been found to increase with an increase in sulfide ion concentration and in. Corrosionpedia what is sulfide stress cracking ssc. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Hydrogen sulfide stress corrosion cracking in materials for. Also, scc is a major issue for steam generator tube integrity in many us pwrs. Ian sutton, in plant design and operations second edition, 2017. The cracking is affected by environmental conditions such as hydrogen sulfide partial pressure and temperature. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfidecontaining solutions has been useful for material selection in many. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide.
Therefore, sulfide precipitates, inclusions and stringers can affect. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking and hydrogen embrittlement of iron base alloys. The stress can be externally applied or it can be an internal residual stress. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
Sulfide stress cracking how is sulfide stress cracking. Stress corrosion cracking is a major issue for rcs system pipes particularly in the weld regions where it is connected to rpv nozzles through safe ends. H 2 s can cause sulfide stress cracking of stainless steels. To check its resistance to scc and ssc, several tests were performed. The primary cause of scc is the residual stress created in the component during manufacturing or fabrication. H 2 s damage can lead to rapid and extensive damage to metals, including uniform corrosion, pitting, and stepwise cracking. Effect of sulfide on the stress corrosion behaviour of a.
Cracking threshold stress is very high, and is assumed to be about 100kgmm 2. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions. Standard test method laboratory testing of metals for. Introduction hydrogen embrittlement produced by sour gas is a critical issue for oil country tubular goods octg products because it causes failure of these components at load levels much lower than the one determined by classical stress design. Copper is known to be susceptible to stress corrosion cracking scc under. In addition, a general comparison is made of the testing requirements for the sulfide stress cracking system and for anodic stress corrosion cracking systems involving hydrogen sulfide. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Hydrogen sulfide is particularly dangerous to equipment when moisture is present. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking nace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world.
Specialized stress corrosion cracking testing capabilities. It should not be confused with the term stress corrosion cracking which is an anodic. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. Iso 151563 will set new restrictions on uns s174000 174ph october 22, 2014 by mariano. Sulfide stress cracking of a pipeline weld in sour gas service. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. In late 2003, it became nace mr0175 iso 15156, petroleum and natural gas industries materials for use in h 2.
Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfide containing solutions has been useful for material selection in many. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. Stress corrosion cracking the international institute of. Sulphide stress cracking ssc is the biggest concern 9. Sulfide stress cracking an overview sciencedirect topics. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogen sulfide h 2 s is a colorless, flammable, and extremely hazardous gas with a strong rotten egg odor. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking. At present there are two main theories for sulfide corrosion cracking, namely hydrogen embrittlement mechanism and stress corrosion cracking mechanism. Hydrogen sulfide stress corrosion cracking of stainless steels. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Standard material requirements sulfide stress cracking. Fundamentals of stress corrosion cracking researchgate.
Wet hydrogen sulfide h2s cracking inspectioneering. Environmental and metallurgical parameters affecting sulfide. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Only reaction of sulfide, moisture and oxygen is necessary. A mechanism of hydrogen insertion in the presence of hydrogen sulfide is also presented. Laboratory testing of metals for resistance to sulfide stress. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion. The stress corrosion cracking behaviour of uns n08031 in. Some researchers consider sulfidestress cracking a type of stress corrosion.
The susceptibility of a high strength low alloy nanostructured steel to sulfide stress corrosion cracking sscc resistance is assessed. Corrosionpedia what is stress corrosion cracking scc. Although there are several kinds of cracking damage that can occur in metals, delayed brittle fracture of metals resulting from the combined action of corrosion in an aqueous sulfide environment and tensile stresses failure may occur at stresses far below the yield stress is the phenomenon known as ssc. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217wc9 cast crmo steel. Reliability of dissimilar metal welds subjected to sulfide. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. In the presence of sulfide corrosion products, such. Stress corrosion cracking recommended practices canadian. In this chapter the terms eac and scc are generally interchangeable. A study on the mechanism of stress corrosion cracking of.
Stresscorrosion cracking in aluminum alloys is characteristically intergranular. Bastien and amiot, mechanism of the effect of ionized. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Stress corrosion cracking wikipedia republished wiki 2. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. For example, in those sealing materials in which aerobic microbial respiration. Sulfide stress cracking nace mr01752002, mr0175iso. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. These comparisons illustrate the need to design environmental cracking tests which reflect both corrosion mechanism factors and application requirements. Tests on statically loaded smooth samples tests on statically loaded precracked samples tests using slowly straining samples more detailed information on these tests can be found in chapter 17, evaluation of stress corrosion cracking, in this book, and in ref 1. Test frames for applying cyclic loads with the measurement of crack propagation rates. Biaxial stress corrosion cracking frames capable of conducting testing in aggressive environments, such as brines with co 2 and h 2 s.
The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Pdf sulfide stress corrosion cracking and hydrogen induced. It can lead to unexpected sudden failure of normally ductile metals subjected to a tensile stress, especially at elevated temperature. Sridhar ramamurthy and andrej atrens stress corrosion. Stress corrosion cracking of low strength, low alloy nickel steels in sulfide environments. The variation of the name is due to the lack of agreement in the mechanism of failure. Stress corrosion cracking in aluminum alloys is characteristically intergranular. Stresscorrosion cracking experiments can be categorized as. Sulfide stress crackingnace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world. Type i mic involves microorganisms that perform anaerobic respiration, while type ii mic. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. Notch tensile slow strain rate testing ntssrt method is used to evaluate the threshold stress intensity values kisscc. The mechanism of stress corrosion cracking is not well understood but it is believed to be caused by stress, corrosive environments and susceptible microstructures.